Triassic mid-oceanic sedimentation in Panthalassa Ocean: Sambosan accretionary complex, Japan     

Tetsuji  Onoue  Hiroyoshi  Sano 《Island Arc》2007,16(1):173-190

Abstract   The Sambosan accretionary complex of southwest Japan was formed during the uppermost Jurassic to lowermost Cretaceous and consists of basaltic rocks, carbonates and siliceous rocks. The Sambosan oceanic rocks were grouped into four stratigraphic successions: (i) Middle Upper Triassic basaltic rock; (ii) Upper Triassic shallow-water limestone; (iii) limestone breccia; and (iv) Middle Middle Triassic to lower Upper Jurassic siliceous rock successions. The basaltic rocks have a geochemical affinity with oceanic island basalt of a normal hotspot origin. The shallow-water limestone, limestone breccia, and siliceous rock successions are interpreted to be sediments on the seamount-top, upper seamount-flank and surrounding ocean floor, respectively. Deposition of the radiolarian chert of the siliceous rock succession took place on the ocean floor in Late Anisian and continued until Middle Jurassic. Oceanic island basalt was erupted to form a seamount by an intraplate volcanism in Late Carnian. Late Triassic shallow-water carbonate sedimentation occurred at the top of this seamount. Accumulation of the radiolarian chert was temporally replaced by Late Carnian to Early Norian deep-water pelagic carbonate sedimentation. Biotic association and lithologic properties of the pelagic carbonates suggest that an enormous production and accumulation of calcareous planktonic biotas occurred in an open-ocean realm of the Panthalassa Ocean in Late Carnian through Early Norian. Upper Norian ribbon chert of the siliceous rock succession contains thin beds of limestone breccia displaced from the shallow-water buildup resting upon the seamount. The shallow-water limestone and siliceous rock successions are nearly coeval with one another and are laterally linked by displaced carbonates in the siliceous rock succession.  相似文献   

大洋多金属结核研究概况   总被引：3，自引：0，他引：3  

杜灵通  吕新彪 《地质与资源》2003,12(3):185-187

从多金属结核的分布及富集规律、物质成分、内部结构、形成机制等方面论述了目前国内外的一些研究动态,对目前在这一研究领域提出的一些新概念、新方法作了一定的介绍.在分析和总结前人研究成果的基础上,指出了在这一研究领域还存在的一些问题及今后研究的方向.  相似文献   

乙醇增强—电感耦合等离子体质谱法直接测定地质样品中碲   总被引：9，自引：3，他引：9       下载免费PDF全文

韩丽荣李冰  马新荣 《岩矿测试》2003,22(2):98-102

建立了HF—HN03密封酸溶以及Na2O2熔融处理样品，乙醇增强灵敏度，电感耦合等离子体质谱直接测定地质样品中微量和超痕量碲的方法。样品溶液中加入乙醇(φ＝4％)，在0．85L/min的载气流速下，碲信号可增强2．5倍以上。碲的方法检出限(100，DF＝1000)为0．02μg/g。用土壤和水系沉积物国家一级标准物质验证了方法的准确度，标准物质的绝大多数分析结果与标准值的误差在允许范围内。分析了大洋多金属结核样品及深海沉积物样品中的微量碲，结果与其他方法相符，精密度试验RSD(n＝3)＜10％。  相似文献   

大洋多金属结核中1nm锰矿相的相变及其主要控制因素研究   总被引：1，自引：3，他引：1  

冯旭文  钱江初  张培志 《矿物学报》2003,23(2):109-114

多金属结核样品在室温中放置或加热干燥后 ,其中的 1nm锰矿相会部分或全部地相变为 0 7nm锰矿相 ,这说明 0 7nm锰矿相可能不是多金属结核的原生锰矿相 ,而仅仅是 1nm锰矿相的相变产物。研究结果表明 :1nm锰矿相结构中的Cu2 + 、Co2 + 、Ni2 + 等金属阳离子的含量与其结构稳定性有正相关关系 ,即金属离子含量越高 ,其结构越稳定 ,1nm锰矿相越不易相变为 0 7nm锰矿相 ,反之亦然 ;另外 ,不同金属阳离子稳定 1nm锰矿相结构的能力也不同 ,结核中几种主要金属阳离子对 1nm锰矿相结构的稳定能力从大到小为 :Ni2 + >Cu2 + >Co2 + >Zn2 + >Ca2 + =Mg2 + 。  相似文献   

华南热水成因硅质岩建造的稀土元素地球化学特征   总被引：11，自引：2，他引：11  

杨海生  周永章  杨志军  张澄博  付伟 《矿物岩石地球化学通报》2003,22(1):61-64

本文在华南地区若干个重要层位热水成因硅质岩建造的稀土元素地球化学数据的基础上,讨论了热水成因硅质岩的REE特征及其与形成环境的关系。指出典型热水沉积建造的δCe为负异常,而δEu为正异常,且LREE>HREE;这种热水成因的硅质岩REE总量普遍较低,且有从热水喷口向外REE总量增高的趋势。热水成因硅质泥岩与正常沉积成因硅质泥的混合存在使稀土元素分布状况变得更复杂。  相似文献   

Permian radiolarians,chert and basalt from the Daxinshan Formation in Lancangjiang belt of southwestern Yunnan,China   总被引：2，自引：0，他引：2  

Qinglai?FengEmail author  Shangyue?Shen  Benpei?Liu  Dietrich?Helmcke  Xianggui?Qian  Weiming?Zhang 《中国科学D辑(英文版)》2002,45(1):63-71

The stratigraphical sequences composed of chert and basalt were found in the Daxinshan area of Simao and the Manbie area of Jinghong, southwestern Yunnan. The Middle Permian to ealiest Late Permian radiolarians, such as Follicucullus and Pseudoalbaillella, have been identified from the chert. The chert from the Manbie area of Jinghong is characterized by high SiO₂content (over 92%), large ratios of MnO/TiO₂ (2.15) and low ratios of Al/(Al+Fe+Mn) (≤0.1) and Ce/Ce*(0.4), which indicate that the chert was deposited in pelagic basin. The chert from the Daxinshan area of Simao, however, is characterized by low SiO₂ content, low ratios of MnO/TiO₂ (0.27) and high ratios of Al/(Al+Fe+Mn) (0.49) and Ce/Ce*(0.88), which imply that the chert was deposited in continental margin basin. The basalts from the both areas belong to tholeiite series, and the chemical compositions of their major, rare earth and trace elements show the characteristics of MORB. These results evidence that there are volcanic rocks and chert sequences representing pelagic basin and oceanic basin near continent. These sequences and the formerly reported island-arc volcanic rock sequences imply that the Daxinshan Formation in the Lancangjiang belt represents a sedimentary assemblage formed in active continental margin basin.  相似文献   

Chemistry and Sulfur Isotopes in a Chert-dominant Sequence around the Stratiform Manganese Deposit of the Noda-Tamagawa Mine, Northern Kitakami Terrane, Northeast Japan: Implication for Paleoceanographic Environmental Setting     

Kosei Komuro    Katsuyuki Yamaguchi  Yoshimichi Kajiwara 《Resource Geology》2005,55(4):337-351

Abstract. Chemistry and sulfur isotopes are analyzed for a series of rocks in the chert‐dominant sequence around the stratiform manganese ore deposit of the Noda‐Tamagawa mine in the northern Kitakami Terrane, northeast Japan. The sequence is litholog‐ically classified into six units in ascending order: lower bedded chert, lower black shale, massive chert, manganese ore, upper black shale, and upper bedded chert. The rocks around the manganese ore deposit exhibit anomalous enrichment in Ni (max. 337 ppm), Zn (102) and U (30) in the upper part of lower bedded chert, Mo (122), Tl (79) and Pb (33) in the lower black shale, MnO, Cu (786) and Co (62) in the manganese ore, and As (247) and Sb (17) in the upper black shale. The aluminum‐normalized profiles reveal zonal enrichment of redox‐sensitive elements around the manganese bed: Zn‐Ni‐Fe‐Mo‐U(‐Co), Tl‐Pb(‐Mo), Mn‐Fe‐Cu‐V‐Cr‐Co(‐Zn) and As‐Sb in ascending order. The uppermost part of the lower bedded chert and black shale exhibit negative Ce/Ce* values, whereas the massive chert, manganese ore and lower part of the upper bedded chert display positive values. The isotopic δ³⁴S values are 0±6 % in the lower part of the lower bedded chert, ‐19 to ‐42 % in the upper part of the lower bedded chert, ‐36 to ‐42 % in the lower black shale, ‐28 to ‐35 % in the massive chert, manganese ore and upper black shale, and ‐23±5 % in the upper bedded chert. Thus, there is a marked negative shift in δ³⁴S values in the lower bedded chert, and an upward‐increasing trend in δ³⁴S through the manganese ore horizon. The present data provide evidence for a change in the paleoceanographic environmental resulting from inflow of oxic deepwater into the stagnant anoxic ocean floor below the manganese ore horizon. This event is likely to have triggered the precipitation of manganese oxyhydroxides. The redistribution of redox‐sensitive elements through the formation of metalliferous black shale and manganese carbonate ore may have occurred in association with bacterial decomposition of organic matter during early diagenesis of initial manganese oxyhydroxides.  相似文献   

Chemical Profiles across a Jurassic Stratiform Manganese Deposit at Katsuyama in the Mino Terrane of Central Japan: Implications for Depositional Environment, Diagenetic Metal Redistribution and Paleoceanography     

Kosei Komuro  Koji Wakita 《Resource Geology》2005,55(4):321-336

Abstract. Inorganic chemical compositions are determined for a series of rocks crossing an Early Jurassic stratiform manganese ore deposit in a chert‐dominant sequence at Katsuyama, in the Mino Terrane of central Japan. The lithology in the vicinity of the manganese ore bed is classified into lower bedded chert, black shale, massive chert, manganese ore and upper bedded chert, in ascending order. The rocks surrounding the manganese deposit are anomalously high in certain elements: Pb (max. 29 ppm), Ni (1140) and Co (336) in the lower bedded chert, Mo (438), As (149), Tl (29) and U (12) in the black shales, V (210) and Cr (87) in the massive chert, and MnO and W (24) in the manganese ore. The aluminum‐normalized profiles reveal a distinct zonation of redox‐sensitive elements: Pb‐Zn, Ni‐Co‐Cu(‐Zn) and U‐Cr in the lower bedded chert, Mo‐As‐Tl in the black shale, V(‐Cr) in the massive chert, and Mn‐Fe‐Ba‐W in the manganese ore, in ascending order. The lower and upper bedded cherts and manganese ore generally exhibit flat rare earth element patterns with positive Ce anomalies, whereas the uppermost part of the lower bedded chert, the black shale and massive chert have flat patterns with weak or nonexistent negative Ce anomalies and weak positive Eu anomalies. The strong enrichment in Ni, Co, W, Tl and As detected in the Katsuyama section is not recognized in other sediments, including those of anoxic deposition origin, but is identified in modern ferromanganese nodules, suggesting that metal enrichment in the Katsuyama section is essentially due to the formation of ferromanganese nodules rather than to deposition in an anoxic environment. The observed elemental zonation is well explained by equilibrium calculations, reflecting early diagenetic formation and associated gradual reduction with depth. The concentration profiles in combination with litho‐ and biostratigraphical features suggest that formation of these bedded manganese deposits was triggered by an influx of warm, saline and oxic water into a stagnant deep ocean floor basin in Panthalassa at the end of the middle Early Jurassic. Paleoceanographic environmental controls thus appear to be important factors in the formation and preservation of this type of stratiform manganese deposit.  相似文献   

湘中南二叠系孤峰组硅质岩的成因属性及其地球动力学指示意义   总被引：5，自引：0，他引：5  

付伟  周永章  杨志军  何俊国  张澄博  杨海生 《矿物岩石地球化学通报》2004,23(4):292-300

华南二叠系底部的硅质岩及同一层位对应于华南重要的地幔强活动期和成矿期，有非常重要的动力学指示意义。研究表明，孤峰组剖面的岩性可划分为三段：泥页岩段、厚层状硅质岩段和薄层状硅质岩段。沿剖面自下而上，Al2O3、K2O和TiO2含量逐渐降低，MnO、TFe等组分逐渐升高；稀土元素显示出一定的铈负异常，∑REE偏低，且向上∑REE逐渐减少而HREE／LREE逐渐增高；一些热水沉积诊断性微量元素如As、Sb、Hg等也显示出一定程度的异常。这些特征均表明硅质岩的成岩过程中包含有正常沉积和热水沉积的共同作用，且自下而上热水沉积作用逐渐增强的趋势。这种成岩作用的演化特征，代表了下扬子地台拉张裂陷盆地对晚古生代伸展背景的沉积响应，对于探讨裂谷盆地阶段性发育的动力学特征有一定的指示意义。  相似文献   

多金属结核的沉积物地球化学场     

杨慧宁  陈永志  沈桂梅 《岩石矿物学杂志》1996,15(4):307-315

远洋沉积物是多金属结核赖以生长的场所，本文系统地研究了沉积物中主要成矿元素水成组分在不同地球化学场和不同沉积阶段的地球化学特征，以及水成组分的含量比与成矿作用的相互关系。研究表明，Ｍｎ、Ｆｅ、Ｃｏ、Ｎｉ、Ｃｕ都是一些比较活泼的元素，它们共处于多金属结核、沉积物和大洋水的统一体系中，当结核形成时，Ｍｎ、Ｆｅ、Ｎｉ、Ｃｕ在结核与沉积物中的含量呈负相关，而Ｃｏ含量呈正相关。研究区东部结核以富含Ｍｎ、Ｎｉ、Ｃｕ贫Ｆｅ、Ｃｏ为特征，其伴生沉积物相对贫Ｍｎ、Ｎｉ、Ｃｕ、Ｃｏ，而富Ｆｅ，可称之为贫化的地球化学场。研究区西部结核富含Ｆｅ、Ｃｏ而贫Ｍｎ、Ｎｉ、Ｃｕ，其伴生沉积物则相应贫Ｆｅ，而富Ｍｎ、Ｎｉ、Ｃｕ、和Ｃｏ，可称之为富化的地球化学场。可以看出，贫化的沉积物地球化学场，恰恰是寻找富矿结核的最佳场所。早中新世以来的沉积物，根据水成组分的含量或含量比，也可相应于结核的形成分为三大沉积阶段，其中的第Ⅱ阶段具有贫化的地球化学特征，是多金属结核形成的最有利时期  相似文献